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SIOResin
May 5, 2025May 9, 2025

Methylhydropolysilazane SIOResin®

SIOResin® SIO-9113 Methylhydropolysilazane is a liquid polysilazane with a Si–N backbone, exhibiting excellent thermal stability and reactivity. It contains reactive Si–H groups in its molecular structure, which can transform into SiCN, SiCNO, or silica-based ceramic materials at high temperatures, making it an ideal precursor for Si–C–N ceramics. When reacted with polymers containing olefin structures via hydrosilylation, it significantly increases ceramic yield (>75%), and is widely used in high-performance ceramics and high-temperature composite materials. Price: $120/L

Methylhydropolysilazane

Download TDS

​​Methyl hydrogeno silazane​​ is a versatile organosilazane compound. It combines reactivity with thermal stability.

​​Key applications include:​​

  • ​​Silane coupling agent​​ for stronger composite interfaces.
  • ​​Precursor conversion​​ to make SiC/Si₃N₄ ceramics for aerospace.
  • ​​CVD/ALD precursor​​ depositing low-k films (Dk<3.2) in semiconductors.
  • Modifying photoresists and polymers for heat resistance.
  • ​​High-adhesion anode additive​​ in lithium batteries.
  • Medical slow-release materials, artifact preservation, and 3D printing resin enhancemen

Technical Specifications

Test ItemPerformance Index
Appearance & ColorLight yellow to colorless transparent liquid
Viscosity (Ford-4 cup)45–60 seconds
Active Ingredient≥95%
Solid Content (120±2℃)>98%
Density (g/mL)1.04 ± 0.01
Molecular Weight>80,000
Hardness (Pencil)≥4H
AdhesionGrade 0 (Excellent)
Salt Spray Resistance>1000 hours

SIOResin® SIO-9113 Methylhydropolysilazane Applications

Resin Modification & Curing Agent

The Si–H and Si–N bonds in SIO-9113 readily react with hydroxyl-containing substances, making it suitable for use as an amine-based curing agent. Manufacturers can also use it to modify phenolic, epoxy, acrylic, and alkyd resins, enhancing their heat resistance, weatherability, and chemical stability.

Ceramics and Rubber Industry

Used as a ceramic precursor for producing high-performance SiCN ceramics. In the rubber industry, it serves as a structural modifier to improve the thermal stability and mechanical strength of silicone and synthetic rubber.

Methyl hydro polysilazane

Curing Conditions

(Relative humidity: 50%, Dry film thickness: 5–25 μm)

Temperature (℃)Tack-Free Time (h)Full Cure Time (h)
1651.01.0
1800.21.0
2000.10.5
2500.10.5

Application Instructions

Standard Process:
Surface Preparation → Sandblasting/Rust Removal → Cleaning & Drying → Coating → Curing

Key Application Notes:

  • Surface Treatment: Remove oxide scale, rust, and oil using sandblasting or abrasive tools. Recommended surface preparation grade is Sa2.5 (optimal), with a minimum of St3.
  • Cleaning & Drying: Use a specialized degreaser or cleaner to treat the surface, ensuring it is thoroughly dried.
  • Product Preparation: This is a single-component liquid. Shake well before use and filter with 120-mesh screen.
  • Application Method: Spray application is recommended (nozzle diameter: 0.5–1.0 mm) for better coating uniformity and appearance.
  • Curing Conditions: For use below 400°C: Heat cure at 180°C for 30 minutes; For use above 400°C: Heat cure at 250°C for 30 minutes.

Methylhydropolysilazane Storage & Transportation Requirements

  1. Store in a dry, cool, and ventilated environment away from heat and open flames. Keep containers sealed and avoid direct sunlight.
  2. Storage temperature: 5–30°C. Shelf life: 6 months.
  3. Reseal any unused material promptly after opening to avoid moisture contamination.
  4. Do not reuse leftover mixed coatings. Dispose of according to local regulations.
  5. Products beyond the shelf life should only be used after passing quality inspection.
polysilazane resin

About SIOResin (SIO New Material)

SIOResin is a leading company in China specializing in the development and production of new materials. We manufacture and supply high-quality silicone resins, silicone-modified polyesters, water-based polyurethanes, water-based acrylics, UV resins, liquid silicone rubber, intumescent fireproof coatings, flame retardants, wetting agents, curing agents, associative thickeners, driers, soft-touch agents, and other additives. Our products have a wide range of applications and with competitive prices.

To learn more or to request samples, feel free to contact us. We are always here to help with your adhesive needs!

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